The 31-year-old who is married to the New England Patriots player for two years raked in USD 45 million in the last year, while Brady, 34, earned USD 31 million, making their combined annual earnings to USD 76 million in 2010, according to Forbes Magazine.
In second place are singer Beyonce Knowles and rapper husband Jay-Z, with an income of USD 72 million.
Following them were Hollywood superstar couple, Brad Pitt and Angelina Jolie, who had a combined income of USD 50 million.
David and Victoria Beckham are at the fourth place with an income of USD 44 million and 'Twilight' stars Robert Pattinson and Kristen Stewart are at the fifth spot with USD 40 million.